Fant 10273 publikasjoner. Viser side 404 av 411:
This study critically examines the workflow for untargeted analysis of volatile organic compounds (VOCs) in ambient air, from sampling strategies to data interpretation by using GC-HRMS. While untargeted approaches are well-established in liquid chromatography (LC) due to advanced-deconvolution tools and extensive metabolomic libraries, their application in gas chromatography (GC) remains less developed, particularly for VOCs. The high structural isomerism of VOCs and the relative novelty of GC-based untargeted methodologies present unique challenges, including limited software tools and reference libraries. Air samples from suburban and rural sites in central Italy were analyzed to explore chemical diversity and address methodological gaps. This study evaluates critical decisions, such as sampling strategies, extraction techniques, and data-processing workflows, highlighting the limitations of automated deconvolution tools and the need for manual validation. Results revealed distinct source contributions, with suburban areas showing higher levels of anthropogenic compounds and rural areas dominated by biogenic emissions. This work underscores the potential of GC-HRMS untargeted analysis to advance environmental chemistry, while addressing key pitfalls and providing practical recommendations for reliable application. By bridging methodological gaps, it offers a roadmap for future studies aiming to integrate untargeted and targeted approaches in air quality research.
2025
Metaller, PCB, PAH og dioksiner i mose i Sør-Varanger. Moseundersøkelser 2008, 2015 og 2020
I 2008 samlet Svanhovd Miljøsenter inn mose ved 11 lokaliteter i grenseområdene mot Russland som NILU analyserte for 11 metaller, PCB, PAH og dioksiner. Formålet var å undersøke om det var andre kilder til forurensning i grenseområdene enn gruvedrift og smelteverksindustri. Prøvetaking og analyse ble gjentatt av NILU i 2015 og 2020, men kun for 60 (2015) og 56 (2020) metaller. For spormetallene Ni, Cu, Co og As er det et klart mønster med forhøyede konsentrasjoner nedstrøms Nikel og Zapolyarnyj. Organiske miljøgifter viser lave konsentrasjoner.
NILU
2025
Global greenhouse gas reconciliation 2022
In this study, we provide an update on the methodology and data used by Deng et al. (2022) to compare the national greenhouse gas inventories (NGHGIs) and atmospheric inversion model ensembles contributed by international research teams coordinated by the Global Carbon Project. The comparison framework uses transparent processing of the net ecosystem exchange fluxes of carbon dioxide (CO2) from inversions to provide estimates of terrestrial carbon stock changes over managed land that can be used to evaluate NGHGIs. For methane (CH4), and nitrous oxide (N2O), we separate anthropogenic emissions from natural sources based directly on the inversion results to make them compatible with NGHGIs. Our global harmonized NGHGI database was updated with inventory data until February 2023 by compiling data from periodical United Nations Framework Convention on Climate Change (UNFCCC) inventories by Annex I countries and sporadic and less detailed emissions reports by non-Annex I countries given by national communications and biennial update reports. For the inversion data, we used an ensemble of 22 global inversions produced for the most recent assessments of the global budgets of CO2, CH4, and N2O coordinated by the Global Carbon Project with ancillary data. The CO2 inversion ensemble in this study goes through 2021, building on our previous report from 1990 to 2019, and includes three new satellite inversions compared to the previous study and an improved managed-land mask. As a result, although significant differences exist between the CO2 inversion estimates, both satellite and in situ inversions over managed lands indicate that Russia and Canada had a larger land carbon sink in recent years than reported in their NGHGIs, while the NGHGIs reported a significant upward trend of carbon sink in Russia but a downward trend in Canada. For CH4 and N2O, the results of the new inversion ensembles are extended to 2020. Rapid increases in anthropogenic CH4 emissions were observed in developing countries, with varying levels of agreement between NGHGIs and inversion results, while developed countries showed a slowly declining or stable trend in emissions. Much denser sampling of atmospheric CO2 and CH4 concentrations by different satellites, coordinated into a global constellation, is expected in the coming years. The methodology proposed here to compare inversion results with NGHGIs can be applied regularly for monitoring the effectiveness of mitigation policy and progress by countries to meet the objectives of their pledges. The dataset constructed for this study is publicly available at https://doi.org/10.5281/zenodo.13887128 (Deng et al., 2024).
2025
2025
2025
Industrial and public infrastructure as local sources of organic contaminants in the Arctic
Arctic pollution has been a focal point in environmental research over the past five decades. Recently, the number of pollutants identified as relevant to the Arctic has significantly increased. Consequently, the expert group on Persistent Organic Pollutants (POPs) and Chemicals of Emerging Arctic Concern (CEACs) of the Arctic Monitoring and Assessment Programme (AMAP) has prepared a series of assessments of contaminants in the Arctic, including influences of climate change. This review addresses local sources of Arctic organic pollutants associated with infrastructure in the Arctic. Industrial, military, and public infrastructures, including domestic installations, sewage treatment, solid waste management, and airports, were identified as significant local pollution sources. Additionally, operational emissions (e.g., from shipping, transportation, heating, and power production) contribute to the overall local pollution profile. Based on currently available scientific information, elevated POP and CEAC levels are mostly found in close proximity to identified local pollution sources. To date, hazardous effects have only been confirmed for a few selected chemicals, such as polycyclic aromatic compounds (PAC) and certain pharmaceutical residues. However, studies are biased in the sense that they often focus on well-known contaminants, at a risk of overlooking CEAC and their effects. The review identifies several measures to reduce human impacts on local Arctic environments, including (i) using local indicator pollutants in ongoing national monitoring schemes, (ii) harmonizing emission reduction policies and licensing of industrial activities in the region to minimize exposure risks and environmental pollution, (iii) encouraging local municipalities, industries, and related stakeholders to coordinate their activities to minimize pollutant emissions.
2025
Monitoring of greenhouse gases and aerosols at Svalbard and Birkenes in 2024. Annual report
This annual report for 2024 summarizes the activities and results of the greenhouse gas monitoring at the Zeppelin Observatory, situated on Svalbard, during the period 2001-2024, and the greenhouse gas monitoring and aerosol observations from Birkenes for 2009-2024.
NILU
2025
Alors que le dépassement du seuil des +1,5°C est désormais inévitable, pour limiter le réchauffement climatique, une nouvelle technique voit peu à...
2025
2025
Methane in Svalbard (SvalGaSess)
Methane is a powerful greenhouse gas whose emission into the atmosphere from Arctic environments is increasing in response to climate change. At present, the increase in atmospheric methane concentrations recorded at Ny-Ålesund and globally threatens the Paris Agreement goal of limiting warming to 2 degrees, preferably 1.5 degrees, by increasing the need for abatements. However, our understanding of the physical, chemical and biological processes that control methane in the Arctic are strongly biased towards just a few lowland sites that are not at all like Svalbard and other similar mountainous, ice-covered regions. Svalbard can therefore be used to better understand these locations. Svalbard’s methane stocks include vast reserves of ancient, geogenic methane trapped beneath glaciers and permafrost. This methane supplements the younger, microbial methane mostly produced in waterlogged soils and wetlands during the summer and early winter. Knowledge about the production, removal and migration of these two methane sources in Svalbard’s complex landscapes and coastal environments has grown rapidly in recent years. However, the need to exploit this knowledge to produce reliable estimates of present-day and future emissions of methane from across the Svalbard landscape is now paramount. This is because understanding these quantities is absolutely necessary when we seek to define how society must adjust in order to better manage greenhouse gases in Earth’s atmosphere
2025
Arctic food and energy security at the crossroads
Arctic food systems blend Traditional Ecological Knowledge with modern, often energy-intensive influences, triggered by colonization. Food systems’ future depends on alignment of tradition with innovation, facilitation of resilience and a heritage-driven interaction with the global economy – at a pace determined by local communities.
2025
Status report of air quality in Europe for year 2024, using validated and up-to-date data
This report presents summarised information on the status of air quality in Europe in 2024, based on Up-To-Date data (i.e. prior to final quality control) and validated air quality monitoring data officially reported by the member and cooperating countries of the EEA. It aims at giving more timely and preliminary information on the status of ambient air quality in Europe in 2024 for five key air pollutants (PM10, PM2.5, O3, NO2 and SO2). The report also gives a preliminary assessment of the progress towards meeting the European air quality standards for the protection of health and the World Health Organization air quality guideline levels, and compares the air quality status in 2024 with the previous years. The preliminary data reported for 2024 shows that 7% and 13% of the monitoring stations exceeded the EU standards for PM10 and O3, respectively. The WHO AQG for PM2.5, PM10, O3 and SO2 were exceeded by 93%, 59%, 98% and 3%, respectively. Exceedances of the NO2 limit value still occur in 7 reporting countries and NO2 WHO AQG occur in all reporting countries.
European Topic Centre on Human Health and the Environment (ETC HE)
2025
2025
Sources of ultrafine particles at a rural midland site in Switzerland
Ultrafine particles (UFPs; i.e., atmospheric aerosol particles smaller than 100 nm in diameter) are known to be responsible for a series of adverse health effects as they can deposit in humans' bodies. So far, most field campaigns studying the sources of UFPs have focused on urban environments. This study investigates the outdoor sources of UFPs at the atmospheric monitoring station in Payerne, which represents a typical rural location in Switzerland. We aim to quantify the primary and secondary fractions of UFPs based on specific measurements between July 2020 and July 2021 complementing a series of operational meteorological, trace gas and in situ aerosol observations. To distinguish between primary and secondary contributions, we use a method that relies on measuring the fraction of non-volatile particles as a proxy for primary particles. We further compare our measurement results to previously established methods. We find that primary particles resulting from traffic and residential wood burning (direct emissions – mostly non-volatile BC-rich) contribute less than 40 % to the total number of UFPs, mostly in the Aitken mode. On the other hand, we observe local new particle formation (NPF) events (observed from ∼ 1 nm) evident from the increase in cluster ions (1.5–3 nm) and nucleation-mode particle (2.5–25 nm) concentrations, especially in spring and summer. These events, mediated by sulfuric acid, contribute to increasing the UFP number concentration, especially in the nucleation mode. Besides NPF, the chemical processing of particles emitted from multiple sources (including traffic and residential wood burning) contributes substantially to the nucleation-mode particle concentration. Under the present conditions investigated here, we find that secondary processes mediate the increase in UFP concentration to levels equivalent to those in urban locations, affecting both air quality and human health.
2025
Tire particles can enter the marine environment e.g. through direct discharge of road runoff, sewage systems or riverine inputs. Their fate in marine waters remains largely unknown, though the deep sea could be a final sink as for other marine litter. To simulate these conditions, we investigated in laboratory-controlled conditions the effects of high-hydrostatic pressure [20 MPa] vs atmospheric pressure [0.1 MPa] on the leaching of 17 organic compounds from cryo-milled tire tread particles (μm sized) and crumb rubber particles (mm sized) into natural seawater. We monitored the abundance of heterotrophic prokaryotes in the leachates over the 14 day exposure period under biotic conditions. Abiotic controls were employed to delineate the influence of prokaryotes on the fate of leached chemicals. Our results showed leaching of dissolved organic carbon and target chemicals under all experimental conditions, with higher concentrations of certain target chemicals under high-hydrostatic pressure conditions (e.g., 1,3-diphenylguanidine [DPG]: max. 703 (20 MPa) vs 119 μg/L (0.1 MPa) from cryo-milled tire tread particles under biotic conditions). Under abiotic conditions leaching was weaker for DPG and other chemicals, with contrasting trends for chemicals prone to biotransformation. In crumb rubber leachates chemical concentrations increased with time, but showed no significant differences between biotic/abiotic or high-hydrostatic/atmospheric pressure conditions. Prokaryotic abundance increased in all samples containing tire particles compared to seawater controls, indicating the use of the rubber and/or leached chemicals as an energy source.
2025
2025
Etablering av vindkraftverk på land kan medføre en risiko for drikkevann når installasjonene ligger i eller nær vanntilsigsområder til drikkevannskilder. Denne rapporten, utarbeidet av VKM på oppdrag fra Mattilsynet, gir Mattilsynet et kunnskapsbasert grunnlag for å stille krav til konsekvensutredninger og detaljplan for å beskytte drikkevannet.
Rapporten identifiserer potensielle farer for kjemisk og fysisk forurensning av drikkevann gjennom hele livsløpet til et vindkraftverk – fra planlegging og anleggsfase, til drift og avvikling. Den beskriver relevante lover og forskrifter, sentrale aktører og deres roller, og legger vekt på når og hvordan Mattilsynet kan involveres og komme med innspill i den kommunale planprosessen etter plan- og bygningsloven og i konsesjonsprosessen etter energiloven som forvaltes av NVE. Det er av stor betydning at Mattilsynet varsles og involveres tidlig i prosessen. Tiltakshaver må sørge for at risiko for forurensning av drikkevann og vanntilsigsområde utredes på en etterprøvbar måte, slik at Mattilsynet kan gi tydelige innspill til utredningen for å sikre at drikkevannshensyn er ivaretatt.
2025
2025